Surfactant modulated interactions of hydrophobically modified ethoxylated urethane (HEUR) polymers with penetrable surfaces

Synthesis of Ethoxylated Urethane and Modification with Cetyl Alcohol as Thickener*

A suitable reaction system, and proper conditions were designed to produce desirable polyurethane base thickener with a calculated number average molecular weight. Initially an ethoxylated urethane prepolymer was synthesized by reaction of a polyethylene glycol (M„=6000) and dicyclohexylmethane diisocyanate using the step growth polymerization technique. Modification was carried out by reaction...

Stabilized by a Hydrophobically Modified Inulin Surfactant

Hydrophobically modified polymers can minimize skin irritation potential caused by surfactant-based cleansers

INTRODUCTION The addition of hydrophobically modified polymers (HMPs) to cleansers that contain surfactants can create polymer-surfactant complexes that are less irritating to the skin than commercially available mild cleansers. Our objective was to compare the tolerability and efficacy of a test foaming liquid facial cleanser containing HMPs with a commercial liquid nonfoaming facial cleanser ...

Synthesis and Characterization of a Nonionic Urethane-Based Thickener

Hydrophobically modified ethoxylated urethanes have been synthesized using polyethylene glycol, hexamethylene diisocyanate and cetyl alcohol. These types of thickeners are categorized as nonionic associative thickeners. The HEURs were prepared in two steps. Initially an ethoxylated urethane prepolymer was synthesized through a reaction between a polyethylene glycol (Mn=6000) and hexamethylene d...

Interactions of a hydrophobically modified polymer with oppositely charged surfactants.

The interaction of a hydrophobically modified anionic polymer (PMAOVE) with a cationic surfactant (DTAB) was studied using a multi-technique approach: turbidity, surface tension, and viscosity measurements, as well as EPR (5-doxyl stearic acid) and fluorescence (pyrene) probe techniques were used. In the investigated pH range (4-10), the cationic surfactant headgroups interact with the anionic ...